The Manchester City duo are part of Gareth Southgate’s 30-man squad for the trio of fixtures at Wembley Stadium this month.
The Three Lions face Wales in a friendly on Thursday 8 October, before back to back UEFA Nations League games against Belgium, on Sunday 11 October and Denmark three days later.
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Having missed the previous six games, Walker was recalled for the matches against Iceland and Denmark last month and needs just one more appearance to reach a milestone 50 caps.
Sterling has been directly involved in 17 goals in his last 13 appearances for the national team, scoring 11 times and providing six assists.
The 25-year-old converted the winning goal from the penalty spot against Iceland in the last round of international fixtures.
England squad
Goalkeepers: Dean Henderson, Jordan Pickford, Nick Pope.
Defenders: Trent Alexander-Arnold, Ben Chilwell, Conor Coady, Eric Dier, Joe Gomez, Michael Keane, Harry Maguire, Ainsley Maitland-Niles, Tyrone Mings, Bukayo Saka, Kieran Trippier, Kyle Walker.
Midfielders: Jordan Henderson, Mason Mount, Kalvin Phillips, Declan Rice, James Ward-Prowse, Harry Winks.
Forwards: Tammy Abraham, Harvey Barnes, Dominic Calvert-Lewin, Jack Grealish, Danny Ings, Harry Kane, Marcus Rashford, Jadon Sancho, Raheem Sterling.
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